百科

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

CAS号：865488-87-5

英文名：(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

分子式：C24H35NO16

分子量：593.532

合成路线

benzyl 4,6-di-O-acetyl-3-O-benzyl-2-O-[3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranosyl]-α-D-mannopyranoside

benzyl 4,6-di-O-acetyl-3-O-benzyl-2-O-[3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranosyl]-α-D-mannopyranoside

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-2-(acetoxymethyl)-6-(((2S,3S,4S,5R,6R)-2,4-bis(benzyloxy)-5-hydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-2-(acetoxymethyl)-6-(((2S,3S,4S,5R,6R)-2,4-bis(benzyloxy)-5-hydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

1323156-38-2

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3S,4R,5R,6S)-5-acetamido-6-(((3S,4S,5S,6R)-5-acetoxy-6-(acetoxymethyl)-2,4-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetate

上游原料

benzyl 4,6-di-O-acetyl-3-O-benzyl-2-O-[3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranosyl]-α-D-mannopyranoside (2R,3S,4R,5R,6S)-5-acetamido-2-(acetoxymethyl)-6-(((2S,3S,4S,5R,6R)-2,4-bis(benzyloxy)-5-hydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate

下游产品

2-(p-iodophenyl)ethyl 2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->2)-α-D-mannopyranosyl-(1->6)-β-D-glucopyranoside 2-(p-iodophenyl)ethyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl-(1->2)-3,4,6-tri-O-acetyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-acetyl-β-D-glucopyranoside