百科

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

CAS号：865535-33-7

英文名：(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

分子式：C40H73NO5SSi2

分子量：736.247

合成路线

865535-32-6

(6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-10-enoic acid methyl ester

865535-33-7

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

865535-29-1

(E)-(6R,7S,8S)-11-Benzyloxy-7-hydroxy-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

865535-33-7

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

865535-30-4

(E)-(6R,7S,8S)-11-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

865535-33-7

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

279227-20-2

(2S)-5-benzyloxy-2-methyl-1-pentanal

865535-33-7

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

865535-31-5

(6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-11-hydroxy-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester

865535-33-7

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-15-triethylsilanyloxy-heptadeca-12,16-dienoic acid methyl ester

上游原料

(2S)-5-benzyloxy-2-methyl-1-pentanal (E)-(6R,7S,8S)-11-Benzyloxy-7-hydroxy-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester (6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-10-enoic acid methyl ester (6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-11-hydroxy-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester (E)-(6R,7S,8S)-11-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

下游产品

(12Z,16E)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-hydroxy-4,4,6,8,12,16-hexamethyl-17-(2-methyl-thiazol-4-yl)-5-oxo-heptadeca-12,16-dienoic acid