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(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

CAS号：865535-47-3

英文名：(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

分子式：C35H58N2O5Si

分子量：614.931

合成路线

865535-32-6

(6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-10-enoic acid methyl ester

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

874452-59-2

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxo-15-triethylsilanyloxy-pentadec-12-enoic acid

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

874452-58-1

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxo-15-triethylsilanyloxy-pentadec-12-enoic acid methyl ester

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

865535-46-2

(6R,7S,8S,15S,Z)-7,15-bis((tert-butyldimethylsilyl)oxy)-15-(1,2-dimethyl-1H-benzo[d]imidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxopentadec-12-enoic acid

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

865535-29-1

(E)-(6R,7S,8S)-11-Benzyloxy-7-hydroxy-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

865535-30-4

(E)-(6R,7S,8S)-11-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

279227-20-2

(2S)-5-benzyloxy-2-methyl-1-pentanal

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

865535-31-5

(6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-11-hydroxy-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester

865535-47-3

(Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-15-hydroxy-4,4,6,8,12-pentamethyl-5-oxo-pentadec-12-enoic acid

上游原料

(2S)-5-benzyloxy-2-methyl-1-pentanal (E)-(6R,7S,8S)-11-Benzyloxy-7-hydroxy-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester (Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxo-15-triethylsilanyloxy-pentadec-12-enoic acid methyl ester (6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-10-enoic acid methyl ester (Z)-(6R,7S,8S,15S)-7-(tert-Butyl-dimethyl-silanyloxy)-15-(1,2-dimethyl-1H-benzoimidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxo-15-triethylsilanyloxy-pentadec-12-enoic acid (6R,7S,8S,15S,Z)-7,15-bis((tert-butyldimethylsilyl)oxy)-15-(1,2-dimethyl-1H-benzo[d]imidazol-5-yl)-4,4,6,8,12-pentamethyl-5-oxopentadec-12-enoic acid (6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-11-hydroxy-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester (E)-(6R,7S,8S)-11-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undec-2-enoic acid methyl ester

下游产品

(Z)-(7R,8S,9S,16S)-16-(1,2-dimethyl-1H-benzoimidazol-5-yl)-8-hydroxy-5,5,7,9,13-pentamethyl-oxacyclohexadec-13-ene-2,6-dione (Z)-(7R,8S,9S,16S)-8-(tert-butyl-dimethyl-silanyloxy)-16-(1,2-dimethyl-1H-benzoimidazol-5-yl)-5,5,7,9,13-pentamethyl-oxacyclohexadec-13-ene-2,6-dione