百科

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

CAS号：866022-09-5

英文名：tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

分子式：C28H48O6Si

分子量：508.763

合成路线

[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol

[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

benzoic acid (1S,3R,4S)-4-(tert-butyldimethylsilanyloxy)-4-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester

benzoic acid (1S,3R,4S)-4-(tert-butyldimethylsilanyloxy)-4-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

benzoic acid (1S,3R,4S)-4-hydroxy-4-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester

benzoic acid (1S,3R,4S)-4-hydroxy-4-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethoxy]dimethylsilane

tert-butyl-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethoxy]dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane

上游原料

benzoic acid (1S,3R,4S)-4-(tert-butyldimethylsilanyloxy)-4-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester [(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol benzoic acid (1S,3R,4S)-4-hydroxy-4-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester tert-butyl-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethoxy]dimethylsilane

下游产品

(S)-4-{(4S,5R)-5-[(1S,2S)-3-(4-methoxybenzyloxy)-1-(tert-butyldimethylsilanyloxy)-2-methylpropyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-4-methoxybutyraldehyde