百科

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

CAS号：866916-67-8

英文名：1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

分子式：C19H38O3Si2

分子量：370.674

合成路线

di-O-acetyl-1,5-anhydro-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

di-O-acetyl-1,5-anhydro-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

tri-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranosyl bromide

tri-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranosyl bromide

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

tetra-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranose

tetra-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranose

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

1,5-anhydro-di-O-(t-butyldimethylsilyl)-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol

上游原料

di-O-acetyl-1,5-anhydro-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol tri-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranosyl bromide tetra-O-acetyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranose

下游产品

(1R,2R,3R,4R,6S,7R)-2,3-di(t-butyldimethylsilyloxy)-4-(t-butyldimethylsilyloxymethyl)bicyclo[4.1.0]heptane-7-carboxylic acid ethyl ester (3R,4R,5R)-3,4-di-(t-butyldimethylsilyloxy)-5-(t-butyldimethylsilyloxymethyl)cyclohexene [(1R,2R,3R,4R,6S,7R)-2,3-di(t-butyldimethylsilyloxy)-4-(t-butyldimethylsilyloxymethyl)bicyclo[4.1.0]hept-7-yl]methanol [(1R,2R,3R,4R,6S,7R)-2,3-di(t-butyldimethylsilyloxy)-4-(t-butyldimethylsilyloxymethyl)bicyclo[4.1.0]hept-7-yl]methyl bis(2,2,2-trichloroethyl) phosphate [(1R,2R,3R,4R,6S,7R)-2,3-di(t-butyldimethylsilyloxy)-4-(t-butyldimethylsilyloxymethyl)bicyclo[4.1.0]hept-7-yl]methyl 2,4-dinitrophenyl ether (3R,4R,5R)-3,4-di-(t-butyldimethylsilyloxy)-5-(hydroxymethyl)cyclohexene