百科

(2R,3aS,4S,5R,5aS,10bS,12bS)-4-Acetoxy-3a-ethyl-5-hydroxy-8-methoxy-6-methyl-2-triisopropylsilanyloxy-2,3,3a,4,5,5a,6,11,12,12b-decahydro-1H-6,12a-diaza-indeno[7,1-cd]fluorene-5-carboxylic acid methyl ester

CAS号：867214-52-6

英文名：(2R,3aS,4S,5R,5aS,10bS,12bS)-4-Acetoxy-3a-ethyl-5-hydroxy-8-methoxy-6-methyl-2-triisopropylsilanyloxy-2,3,3a,4,5,5a,6,11,12,12b-decahydro-1H-6,12a-diaza-indeno[7,1-cd]fluorene-5-carboxylic acid methyl ester

分子式：C34H54N2O7Si

分子量：630.887

合成路线

867214-50-4

methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-3a-ethyl-4-hydroxy-8-methoxy-6-methyl-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

867214-52-6

(2R,3aS,4S,5R,5aS,10bS,12bS)-4-Acetoxy-3a-ethyl-5-hydroxy-8-methoxy-6-methyl-2-triisopropylsilanyloxy-2,3,3a,4,5,5a,6,11,12,12b-decahydro-1H-6,12a-diaza-indeno[7,1-cd]fluorene-5-carboxylic acid methyl ester

867214-51-5

methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-acetoxy-3a-ethyl-8-methoxy-6-methyl-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

867214-52-6

867214-15-1

5-[2-(6-Methoxy-1-methyl-1H-indol-3-yl)-ethylamino]-[1,3,4]oxadiazole-2-carboxylic acid methyl ester

867214-52-6

867214-13-9

methyl 2-(2-((2-(6-methoxy-1-methyl-1H-indol-3-yl)ethyl)carbamoyl)hydrazineyl)-2-oxoacetate

867214-52-6

910559-34-1

methyl (3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-oxo-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

867214-52-6

867214-45-7

methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-oxo-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

867214-52-6

910559-45-4

methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-thioxo-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

867214-52-6

上游原料

methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-3a-ethyl-4-hydroxy-8-methoxy-6-methyl-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-acetoxy-3a-ethyl-8-methoxy-6-methyl-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-thioxo-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate 5-[2-(6-Methoxy-1-methyl-1H-indol-3-yl)-ethylamino]-[1,3,4]oxadiazole-2-carboxylic acid methyl ester methyl 2-(2-((2-(6-methoxy-1-methyl-1H-indol-3-yl)ethyl)carbamoyl)hydrazineyl)-2-oxoacetate methyl (3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-oxo-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate methyl (2R,3aR,3a1S,4S,5R,5aS,10bR)-4-(benzyloxy)-3a-ethyl-8-methoxy-6-methyl-1-oxo-2-((triisopropylsilyl)oxy)-2,3,3a,4,5a,6,11,12-octahydro-3a1,5-epoxyindolizino[8,1-cd]carbazole-5(1H)-carboxylate

下游产品

ent-(+)-vindoline (2R,3aS,4S,5R,5aS,10bS,12bS)-4-Acetoxy-3a-ethyl-2,5-dihydroxy-8-methoxy-6-methyl-2,3,3a,4,5,5a,6,11,12,12b-decahydro-1H-6,12a-diaza-indeno[7,1-cd]fluorene-5-carboxylic acid methyl ester