百科

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

CAS号：868048-03-7

英文名：(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

分子式：C9H12O3

分子量：168.19

合成路线

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

(S)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

(S)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

(1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one

上游原料

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one (S)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

下游产品

(1S,3R,4S)-3-hydroxymethyl-4-methoxymethoxy-2,2,4-trimethyl-cyclohexanol (1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde (1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol hydroxy-(3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexyl)-acetonitrile ((1S,2S)-2-methoxymethoxy-2,6,6-trimethyl-cyclohexyl)-acetonitrile (1S,2S,5S)-2-methoxymethoxy-2,8,8-trimethyl-6-oxabicyclo[3.2.1]octan-7-one