百科

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

CAS号：868150-27-0

英文名：(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

分子式：C36H48O7

分子量：592.762

合成路线

(2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-hex-5-yn-2-ol

(2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-hex-5-yn-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

{(2R,3R)-3-[1-((2R,3R)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-ylethynyl}-trimethyl-silane

{(2R,3R)-3-[1-((2R,3R)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-ylethynyl}-trimethyl-silane

Acetic acid (1S,2R)-1-(4-methoxy-benzyloxymethyl)-2-methyl-pent-4-ynyl ester

Acetic acid (1S,2R)-1-(4-methoxy-benzyloxymethyl)-2-methyl-pent-4-ynyl ester

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

(2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-6-trimethylsilanyl-hex-5-yn-2-ol

(2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-6-trimethylsilanyl-hex-5-yn-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

(E)-(2S,3R)-8-{(2R,3R)-3-[1-((2R,3R)-3-Ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxy)-3-methyl-5-methylene-oct-7-en-2-ol

上游原料

(2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-hex-5-yn-2-ol (2S,3R)-1-(4-Methoxy-benzyloxy)-3-methyl-6-trimethylsilanyl-hex-5-yn-2-ol {(2R,3R)-3-[1-((2R,3R)-3-Allyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-ylethynyl}-trimethyl-silane Acetic acid (1S,2R)-1-(4-methoxy-benzyloxymethyl)-2-methyl-pent-4-ynyl ester

下游产品

(E)-3-Methyl-hexa-2,5-dienoic acid (E)-(1S,2R)-7-{(2R,3R)-3-[1-((2R,3R)-3-ethynyl-1,4-dioxa-spiro[4.4]non-2-yl)-vinyl]-1,4-dioxa-spiro[4.4]non-2-yl}-1-(4-methoxy-benzyloxymethyl)-2-methyl-4-methylene-hept-6-enyl ester