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(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

CAS号：868267-00-9

英文名：(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

分子式：C36H64O7Si2

分子量：665.06

合成路线

(8S,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol

(8S,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol

(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

(8R,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol

(8R,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol

(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-methylene-butyl]-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-ol

上游原料

(8R,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol (8S,10R,12S,15R)-15-((R)-4-Hydroxy-3-methyl-2-methylene-butyl)-10-(4-methoxy-benzyloxymethyl)-9,14-dioxa-1,5-dithia-dispiro[5.1.5.3]hexadecan-12-ol

下游产品

tert-butyl(((2R,4S,6R,8S,10S)-8-((E)-2-((dicyclohexylboraneyl)oxy)but-2-en-1-yl)-10-methoxy-2-(((4-methoxybenzyl)oxy)methyl)-1,7-dioxaspiro[5.5]undecan-4-yl)oxy)dimethylsilane [4-acetoxy-8-(2-{2-acetoxy-5-[10-(tert-butyl-dimethyl-silanyloxy)-8-formyl-4-methoxy-1,7-dioxa-spiro[5.5]undec-2-yl]-1,3-dimethyl-4-oxo-pentyl}-allyl)-10-methyl-10-triethylsilanyloxy-1,7-dioxa-spiro[5.5]undec-2-yl]-acetic acid allyl ester (R)-3-[(2R,4S,6R,8R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-8-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undec-2-ylmethyl]-2-methyl-but-3-en-1-ol