百科

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

CAS号：868668-24-0

英文名：(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

分子式：C20H28N2O4

分子量：360.447

合成路线

(4S,6R)-7-(p-methoxybenzyloxy)-6-methyl-1,4-heptanediol

(4S,6R)-7-(p-methoxybenzyloxy)-6-methyl-1,4-heptanediol

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(2R,4S)-4-allyloxy-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methylheptane

(2R,4S)-4-allyloxy-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methylheptane

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(2R,4S)-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methyl-4-heptanediol

(2R,4S)-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methyl-4-heptanediol

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(4S,6R)-4-allyloxy-7-(p-methoxybenzyloxy)-6-methyl-1-heptanol

(4S,6R)-4-allyloxy-7-(p-methoxybenzyloxy)-6-methyl-1-heptanol

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

(5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone

上游原料

(4S,6R)-4-allyloxy-7-(p-methoxybenzyloxy)-6-methyl-1-heptanol (2R,4S)-4-allyloxy-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methylheptane (4S,6R)-7-(p-methoxybenzyloxy)-6-methyl-1,4-heptanediol (2R,4S)-7-(tert-butyldimethylsilyloxy)-1-(p-methoxybenzyloxy)-2-methyl-4-heptanediol

下游产品

{(2R,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-tetrahydro-pyran-2-yl}-acetaldehyde (2R,3SR,6S)-2-allyl-6-[(2R)-3-(p-methoxybenzyloxy)-2-methylpropyl]tetrahydropyran-3-ol {(2R,6S)-2-Allyl-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-tetrahydro-pyran-3-yloxy}-tert-butyl-dimethyl-silane (2R,6S)-2-[2-(tert-butyldimethylsilyloxy)ethyl]-6-[(2R)-3-(p-methoxybenzyloxy)-2-methylpropyl]tetrahydropyran-3-one (2R,6S)-2-(2-Hydroxy-ethyl)-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-tetrahydro-pyran-3-ol Trifluoro-methanesulfonic acid (2R,6R)-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-5,6-dihydro-2H-pyran-3-yl ester (2R,6S)-2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-tetrahydro-pyran-3-ol 2-{(2R,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-tetrahydro-pyran-2-yl}-ethanol