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(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
CAS号:869210-90-2
英文名:(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
分子式:C20H24O5
分子量:344.402
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合成路线
897014-73-2
3-((6E,8E,10E)-(2R,4S)-1-Hydroxy-2,4-dimethyl-5-oxo-dodeca-6,8,10-trienyl)-4-methoxy-5-methylene-5H-furan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-80-1
3-[(2R,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-pentyl]-4-methoxy-5-methylene-5H-furan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-81-2
(2S,4R)-5-(4-Methoxy-benzyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentanal
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
871829-02-6
(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
871829-04-8
(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-oxo-dodeca-8,10-dienal
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
871829-08-2
(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-78-7
Acetic acid (2S,4R)-5-(4-methoxy-benzyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentyl ester
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-83-4
3-[(6E,8E,10E)-(2R,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-dodeca-6,8,10-trienyl]-4-methoxy-5-methylene-5H-furan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-84-5
4-Methoxy-3-[(6E,8E,10E)-(2R,4S)-1-(4-methoxy-benzyloxy)-2,4-dimethyl-5-oxo-dodeca-6,8,10-trienyl]-5-methylene-5H-furan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
897014-72-1
3-[(6E,8E,10E)-(2R,4S)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4-dimethyl-dodeca-6,8,10-trienyl]-4-methoxy-5-methylene-5H-furan-2-one
869210-90-2
(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione
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上游原料
(2S,4R)-5-(4-Methoxy-benzyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentanal
3-[(6E,8E,10E)-(2R,4S)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4-dimethyl-dodeca-6,8,10-trienyl]-4-methoxy-5-methylene-5H-furan-2-one
3-[(2R,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-pentyl]-4-methoxy-5-methylene-5H-furan-2-one
(+)-(2S,4R)-cis-2,4-dimethyl-δ-valerolactone
3-[(2R,4S)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyl]-4-methoxy-5-methylene-5H-furan-2-one
3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one
Acetic acid (2S,4R)-5-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentyl ester
Acetic acid (2S,4R)-5-(4-methoxy-benzyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentyl ester
(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one
(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-oxo-dodeca-8,10-dienal
3-((6E,8E,10E)-(2R,4S)-1,5-Dihydroxy-2,4-dimethyl-dodeca-6,8,10-trienyl)-4-methoxy-5-methylene-5H-furan-2-one
(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one
4-Methoxy-3-[(6E,8E,10E)-(2R,4S)-1-(4-methoxy-benzyloxy)-2,4-dimethyl-5-oxo-dodeca-6,8,10-trienyl]-5-methylene-5H-furan-2-one
3-[(6E,8E,10E)-(2R,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-dodeca-6,8,10-trienyl]-4-methoxy-5-methylene-5H-furan-2-one
3-[1,5-dioxo-(2R,4S)-2,4-dimethyl-(6E,8E,10E)-dodecatrien]-4-methoxy-5-methylene-5H-furan-2-one
(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one
3-((6E,8E,10E)-(2R,4S)-1-Hydroxy-2,4-dimethyl-5-oxo-dodeca-6,8,10-trienyl)-4-methoxy-5-methylene-5H-furan-2-one
(2S,4R)-5-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-pentanal
下游产品
(1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-methoxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione
(1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-hydroxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione