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tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

CAS号：869384-96-3

英文名：tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

分子式：C33H54N2O5Si

分子量：586.878

合成路线

5-{tert-Butoxycarbonyl-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-amino}-pentanoic acid methyl ester

5-{tert-Butoxycarbonyl-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-amino}-pentanoic acid methyl ester

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

(3S,4R,E)-4-(benzyloxy)-3-methyl-6-phenylhex-5-enenitrile

(3S,4R,E)-4-(benzyloxy)-3-methyl-6-phenylhex-5-enenitrile

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

methyl 5-(allyl(tert-butoxycarbonyl)amino)pentanoate

methyl 5-(allyl(tert-butoxycarbonyl)amino)pentanoate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

(2S,3S,E)-3-(benzyloxy)-2-methyl-5-phenylpent-4-en-1-ol

(2S,3S,E)-3-(benzyloxy)-2-methyl-5-phenylpent-4-en-1-ol

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

11,11-dihydroxy-34,94,114-dodecaoxidane-3,9-dione

11,11-dihydroxy-34,94,114-dodecaoxidane-3,9-dione

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

(2S,3S)-1,3-dihydroxy-2-methyl-5-phenyl-4-pentene

(2S,3S)-1,3-dihydroxy-2-methyl-5-phenyl-4-pentene

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

(R)-4-benzyl-3-((2R,3S,E)-3-hydroxy-2-methyl-5-phenylpent-4-enoyl)oxazolidin-2-one

(R)-4-benzyl-3-((2R,3S,E)-3-hydroxy-2-methyl-5-phenylpent-4-enoyl)oxazolidin-2-one

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

tert-butyl (8R,9S,E)-8-benzyloxy-10-cyano-9-methyl-5-oxodec-6-enyl(3-(tert-butyldimethylsilyloxy)propyl)carbamate

上游原料

(3S,4R,E)-4-(benzyloxy)-3-methyl-6-phenylhex-5-enenitrile (2S,3S)-1,3-dihydroxy-2-methyl-5-phenyl-4-pentene 5-{tert-Butoxycarbonyl-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-amino}-pentanoic acid methyl ester (2S,3S,E)-3-(benzyloxy)-2-methyl-5-phenylpent-4-en-1-ol (R)-4-benzyl-3-((2R,3S,E)-3-hydroxy-2-methyl-5-phenylpent-4-enoyl)oxazolidin-2-one methyl 5-(allyl(tert-butoxycarbonyl)amino)pentanoate

下游产品

(10aS,11R,12S,14aS)-4-tert-butyl 14a-ethyl 11-benzyloxy-12-methyl-9,14-dioxotetradecahydrobenzo[e][1]azacyclododecine-4,14a(1H)-dicarboxylate