百科

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

CAS号：870075-02-8

英文名：tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

分子式：C27H47IO3Si

分子量：574.65

合成路线

(Z)-(2S,3R,4R,5S,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-dec-7-en-1-ol

(Z)-(2S,3R,4R,5S,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-dec-7-en-1-ol

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

(2R,3R,4R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-trityloxy-heptanal

(2R,3R,4R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-trityloxy-heptanal

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1R,2R,3S,4S)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-1-((S)-1-methyl-2-trityloxy-ethyl)-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1R,2R,3S,4S)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-1-((S)-1-methyl-2-trityloxy-ethyl)-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-(1S,2R,3S,4S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-oct-5-enyloxy]-dimethyl-silane

上游原料

tert-Butyl-[(Z)-(1R,2R,3S,4S)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-1-((S)-1-methyl-2-trityloxy-ethyl)-oct-5-enyloxy]-dimethyl-silane (2R,3R,4R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-trityloxy-heptanal (Z)-(2S,3R,4R,5S,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-dec-7-en-1-ol

下游产品

Carbamic acid (6Z,11Z)-(1S,2R,3R,4S,8S,9S,10S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-13-hydroxy-2,4,6,8,10-pentamethyl-1-((Z)-(S)-1-methyl-pent-2-enyl)-trideca-6,11-dienyl ester Carbamic acid (6Z,11Z)-(1S,2R,3R,4S,8S,9S,10S,13S)-3,13-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-2,4,6,8,10-pentamethyl-14-((2S,3R)-3-methyl-6-oxo-tetrahydro-pyran-2-yl)-1-((Z)-(S)-1-methyl-pent-2-enyl)-tetradeca-6,11-dienyl ester Carbamic acid (6Z,11Z)-(1S,2R,3R,4S,8S,9S,10S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-2,4,6,8,10-pentamethyl-1-((Z)-(S)-1-methyl-pent-2-enyl)-13-oxo-trideca-6,11-dienyl ester Carbamic acid (6Z,11Z)-(1S,2R,3R,4S,8S,9S,10S,13S,16R,18R)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-13-hydroxy-18-(methoxy-methyl-carbamoyl)-2,4,6,8,10,16-hexamethyl-1-((Z)-(S)-1-methyl-pent-2-enyl)-15-oxo-nonadeca-6,11-dienyl ester (5R,6S)-6-[(3Z,8Z,16Z)-(2S,5S,6S,7S,11S,12R,13R,14S,15S)-2,12-Bis-(tert-butyl-dimethyl-silanyloxy)-14-hydroxy-6-methoxymethoxy-5,7,9,11,13,15-hexamethyl-nonadeca-3,8,16-trienyl]-5-methyl-tetrahydro-pyran-2-one (5R,6S)-6-[(3Z,8Z,16Z)-(2S,5S,6S,7S,11S,12R,13R,14S,15S)-2,12-Bis-(tert-butyl-dimethyl-silanyloxy)-14-(4-methoxy-benzyloxy)-6-methoxymethoxy-5,7,9,11,13,15-hexamethyl-nonadeca-3,8,16-trienyl]-5-methyl-tetrahydro-pyran-2-one (5Z,13Z)-(2S,3R,4S,8S,9R,10R,11S,12S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-2,4,6,8,10,12-hexamethyl-hexadeca-5,13-diene-1,11-diol (5Z,13Z)-(2S,3R,4S,8S,9R,10R,11S,12S)-9-(tert-Butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-hexadeca-5,13-dien-1-ol (2Z,7Z,15Z)-(4S,5S,6S,10S,11R,12R,13S,14S)-5,11-Bis-(tert-butyl-dimethyl-silanyloxy)-13-hydroxy-4,6,8,10,12,14-hexamethyl-octadeca-2,7,15-trienoic acid methyl ester