百科

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

CAS号：871236-67-8

英文名：1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

分子式：C29H56O4Si2

分子量：524.924

合成路线

(−)-(2S,3R,4S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-1-ol

(−)-(2S,3R,4S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-1-ol

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

2,4-dideoxy-3-O-[(1,1-dimethylethyl)dimethylsilyl]-5-O-[(4-methoxyphenyl)-methyl]-2,4-dimethyl-L-arabinose

2,4-dideoxy-3-O-[(1,1-dimethylethyl)dimethylsilyl]-5-O-[(4-methoxyphenyl)-methyl]-2,4-dimethyl-L-arabinose

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

1-((2S,3R,4S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4-dimethylheptyloxy)methyl-4-methoxybenzene

上游原料

2,4-dideoxy-3-O-[(1,1-dimethylethyl)dimethylsilyl]-5-O-[(4-methoxyphenyl)-methyl]-2,4-dimethyl-L-arabinose (−)-(2S,3R,4S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-1-ol

下游产品

(2R,8S,9R,10S,11Z,13S,15S,16R,17E)-9,13,15-tris(tert-butyldimethylsilyloxy)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-8,10,16-trimethyl-19-(trityloxy)nonadeca-11,17-dien-3-one (3S,4R,5S)-4,8-bis(tert-butyldimethylsilyloxy)-3,5-dimethyloct-1-yne (2R,4E,8S,9R,10S,11Z,13S,15S,16R,17E)-9,15-bis(tert-butyldimethylsilyloxy)-13-(tert-butyldimethylsilyloxy)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-8,10,16-trimethyl-19-(trityloxy)nonadeca-4,11,17-trien-3-one (4R,5S,7S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadec-2-en-8-yn-7-ol (4S,5S)-4-((2R,3R,8S,9R,10S,11Z,13S,15S,16R,17E)-3,9,13,15-tetrakis(tert-butyldimethylsilyloxy)-8,10,16-trimethyl-19-(trityloxy)nonadeca-11,17-dien-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxane (2E,4R,5S,7S,8Z,10S,11R,12S)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-(trityloxy)pentadeca-2,8-dien-7-ol (4R,5S,10S,11R,12S,E)-5,11,15-tris(tert-butyldimethylsilyloxy)-4,10,12-trimethyl-1-trityloxypentadec-2-en-8-yn-7-one (4S,5R,6S,7Z,9S,11S,12R,13E)-5,9,11-tris(tert-butyldimethylsilyloxy)-4,6,12-trimethyl-15-(trityloxy)pentadeca-7,13-dien-1-ol ((2E,4R,5S,7S,8Z,10S,11R,12S)-5,7,11,15-tetrakis(tert-butyldimethylsilyloxy)-4,10,12-trimethylpentadeca-2,8-dienyloxy)triphenylmethane (2S,3R,8S,9R,10S,11Z,13S,15S,16R,17E)-9,13,15-tris(tert-butyldimethylsilyloxy)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-8,10,16-trimethyl-19-(trityloxy)nonadeca-11,17-dien-3-ol