百科

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

CAS号：871690-13-0

英文名：(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

分子式：C17H28O6

分子量：328.401

合成路线

(S)-2-Methoxymethoxy-hex-5-enoic acid (R)-1-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-butyl ester

(S)-2-Methoxymethoxy-hex-5-enoic acid (R)-1-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-butyl ester

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(Z)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(Z)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(4R,5S)-2,2-dimethyl-4-((R)-oxiran-2-yl)-5-vinyl-1,3-dioxolane

(4R,5S)-2,2-dimethyl-4-((R)-oxiran-2-yl)-5-vinyl-1,3-dioxolane

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(S)-2-(methoxymethyloxy)hex-5-en-1-ol

(S)-2-(methoxymethyloxy)hex-5-en-1-ol

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(S)-2-(methoxymethyloxy)hex-5-enoic acid

(S)-2-(methoxymethyloxy)hex-5-enoic acid

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(S)-1-(tert-butyldiphenylsilyloxy)-2-(methoxymethyloxy)hex-5-ene

(S)-1-(tert-butyldiphenylsilyloxy)-2-(methoxymethyloxy)hex-5-ene

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(1R)-1-[(4R,5S)-2,2-dimethyl-5-ethenyl-1,3-dioxolan-4-yl]butan-1-ol

(1R)-1-[(4R,5S)-2,2-dimethyl-5-ethenyl-1,3-dioxolan-4-yl]butan-1-ol

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,7S,11aS)-7-Methoxymethoxy-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

上游原料

(S)-1-(tert-butyldiphenylsilyloxy)-2-(methoxymethyloxy)hex-5-ene (1R)-1-[(4R,5S)-2,2-dimethyl-5-ethenyl-1,3-dioxolan-4-yl]butan-1-ol (4R,5S)-2,2-dimethyl-4-((R)-oxiran-2-yl)-5-vinyl-1,3-dioxolane (S)-2-(methoxymethyloxy)hex-5-enoic acid (S)-2-Methoxymethoxy-hex-5-enoic acid (R)-1-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-butyl ester (S)-2-(methoxymethyloxy)hex-5-en-1-ol

下游产品

(+)-lethaloxin (2E,4E)-Hexa-2,4-dienoic acid (E)-(3aR,4R,7S,11aS)-2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester