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3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

CAS号：871829-05-9

英文名：3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

分子式：C26H42O6Si

分子量：478.694

合成路线

(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

3-[(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-2,4-dimethyl-5-oxo-dodeca-8,10-dienyl]-4-methoxy-5-methylene-5H-furan-2-one

上游原料

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one (8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one (3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

下游产品

(E)-(1R,3R,6S,10S,12R)-17-Methoxy-3,10,12-trimethyl-16-oxa-tricyclo[12.2.1.01,6]heptadeca-4,7,14(17)-triene-9,13,15-trione (1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-methoxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione (1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-hydroxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione 3-[1,5-dioxo-(2R,4S)-2,4-dimethyl-(6E,8E,10E)-dodecatrien]-4-methoxy-5-methylene-5H-furan-2-one