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(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

CAS号：871829-06-0

英文名：(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

分子式：C26H40O6Si

分子量：476.678

合成路线

(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

(3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-oxo-dodeca-8,10-dienal

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-oxo-dodeca-8,10-dienal

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-5-methylene-2-oxo-2,5-dihydro-furan-3-yl)-2,4-dimethyl-dodeca-8,10-diene-1,5-dione

上游原料

(8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one (8E,10E)-(2R,4S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-5-oxo-dodeca-8,10-dienal (8E,10E)-(2R,4S)-7-Hydroxy-2,4-dimethyl-1-triethylsilanyloxy-dodeca-8,10-dien-5-one (3S,5R)-3,5-Dimethyl-6-triethylsilanyloxy-hexan-2-one

下游产品

(1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-methoxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione (1aS,2R,3aR,6E,8R,10S,12E,13aR,13bR)-14-hydroxy-2,8,10-trimethyl-2,3,9,10,13a,13b-hexahydro-5H-3a,6-(metheno)oxireno[2',3':3,4]benzo[1,2-b][1]oxacyclododecine-5,7,11(1aH,8H)-trione 3-[1,5-dioxo-(2R,4S)-2,4-dimethyl-(6E,8E,10E)-dodecatrien]-4-methoxy-5-methylene-5H-furan-2-one