百科

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

CAS号：872185-91-6

英文名：(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

分子式：C26H36O6Si

分子量：472.646

合成路线

(1S,5R,6S)-5-hydroxy-4-(hydroxymethyl)-3-iodo-7-oxabicyclo[4.1.0]hept-3-en-2-one

(1S,5R,6S)-5-hydroxy-4-(hydroxymethyl)-3-iodo-7-oxabicyclo[4.1.0]hept-3-en-2-one

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-4-iodo-5-oxo-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-4-iodo-5-oxo-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1S,2R,6S)-2-Hydroxy-4-iodo-5-oxo-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carbaldehyde

(1S,2R,6S)-2-Hydroxy-4-iodo-5-oxo-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carbaldehyde

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

(1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid 4-methoxybenzyl ester

上游原料

(1S,2R,6S)-2-Hydroxy-4-iodo-5-oxo-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carbaldehyde (1S,5R,6S)-5-hydroxy-4-(hydroxymethyl)-3-iodo-7-oxabicyclo[4.1.0]hept-3-en-2-one (1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-4-iodo-5-oxo-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid

下游产品

(2S,3R,7S,11S)-3-{[tert-butyl(dimethyl)silyl]oxy}-7-propyl-1,6-dioxatricyclo[8.1.0.04,9]undec-8-ene-5,10-dione (1R,2R,6S)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-oxo-4-(pent-1-enyl)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid (2R,3R,7S,11S)-3-{[tert-butyl(dimethyl)silyl]oxy}-7-propyl-1,6-dioxatricyclo[8.1.0.04,9]undec-8-ene-5,10-dione