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(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

CAS号：872591-58-7

英文名：(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

分子式：C49H76O6Si3

分子量：845.381

合成路线

(4S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-hexanoic acid methoxy-methyl-amide

(4S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-hexanoic acid methoxy-methyl-amide

Triethyl-[(1R,2S)-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-ynyloxy]-silane

Triethyl-[(1R,2S)-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-ynyloxy]-silane

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

[(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane

[(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(E)-(4S,5R)-5-Hydroxy-6-(4-methoxy-benzyloxy)-4-methyl-hex-2-enoic acid methoxy-methyl-amide

(E)-(4S,5R)-5-Hydroxy-6-(4-methoxy-benzyloxy)-4-methyl-hex-2-enoic acid methoxy-methyl-amide

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(4S,5R)-5,6-Dihydroxy-4-methyl-hexanoic acid methoxy-methyl-amide

(4S,5R)-5,6-Dihydroxy-4-methyl-hexanoic acid methoxy-methyl-amide

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

(2R,3S,9S,10R)-11-(tert-butyl-diphenyl-silanyloxy)-1-(4-methoxy-benzyloxy)-3,9-dimethyl-2,10-bis-(triethyl-silanyloxy)-undec-4-yn-6-one

上游原料

(4S,5R)-5,6-Dihydroxy-4-methyl-hexanoic acid methoxy-methyl-amide (E)-(4S,5R)-5-Hydroxy-6-(4-methoxy-benzyloxy)-4-methyl-hex-2-enoic acid methoxy-methyl-amide (4S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-hexanoic acid methoxy-methyl-amide [(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane Triethyl-[(1R,2S)-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-ynyloxy]-silane

下游产品

(3S,4R)-1-[(2R,5S,6R)-6(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-3-methyl-oct-6-yn-4-ol {[(2R,3S)-tetrahydro-6-methoxy-3-methyl-6-{(S)-3-[(S)-oxiran-2-yl]but-1-ynyl}-2H-pyran-2-yl]methoxy}(tert-butyl)diphenylsilane