百科

(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol

(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol

CAS号：873949-46-3

英文名：(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol

分子式：C28H48O4Si

分子量：476.764

下游产品

(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one

(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one

(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethanol

(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethanol

(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate

(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate

(-)-(3aR,4R,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one

(-)-(3aR,4R,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one

5-[(3aS,4R,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(E)-(3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-oct-1-en-6-ynyl]-hexahydro-pentalen-(2E)-ylidene]-pentanal

5-[(3aS,4R,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(E)-(3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-oct-1-en-6-ynyl]-hexahydro-pentalen-(2E)-ylidene]-pentanal

(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol

(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol

(+)-tert-butyl ((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)pentyloxy)dimethylsilane

(+)-tert-butyl ((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)pentyloxy)dimethylsilane

(+)-(E)-((1S,2R)-2-(2-phenylpropan-2-yl)cyclohexyl)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)acetate

(+)-(E)-((1S,2R)-2-(2-phenylpropan-2-yl)cyclohexyl)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)acetate

(+)-(tert-butyl)-2-((E)-((3aS,4R,5R,6aS)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethoxy)acetate

(+)-(tert-butyl)-2-((E)-((3aS,4R,5R,6aS)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethoxy)acetate

上游原料

(-)-tert-butyldimethyl((3S,4S,E)-4-methyl-1-(tributylstannyl)oct-1-en-6-yn-3-yloxy)silane (3'aS,4'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethyltetrahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'(3'H)-one 1-((3aR,6aS)-5',5'-dimethyl-3,3a,4,6a-tetrahydro-1H-spiro[pentalene-2,2'-[1,3]dioxan]-5-yl)-2-tosyldiazene

下游产品

(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one (+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethanol (+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate (-)-(3aR,4R,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one 5-[(3aS,4R,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(E)-(3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-oct-1-en-6-ynyl]-hexahydro-pentalen-(2E)-ylidene]-pentanal (+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol (+)-tert-butyl ((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)pentyloxy)dimethylsilane (+)-(E)-((1S,2R)-2-(2-phenylpropan-2-yl)cyclohexyl)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)acetate (+)-(tert-butyl)-2-((E)-((3aS,4R,5R,6aS)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethoxy)acetate