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(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol
CAS号:873949-46-3
英文名:(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol
分子式:C28H48O4Si
分子量:476.764
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合成路线
873949-45-2
(3'aS,4'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethyltetrahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'(3'H)-one
873949-46-3
(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol
873949-42-9
(-)-tert-butyldimethyl((3S,4S,E)-4-methyl-1-(tributylstannyl)oct-1-en-6-yn-3-yloxy)silane
431041-20-2
1-((3aR,6aS)-5',5'-dimethyl-3,3a,4,6a-tetrahydro-1H-spiro[pentalene-2,2'-[1,3]dioxan]-5-yl)-2-tosyldiazene
873949-46-3
(+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol
上游原料
(-)-tert-butyldimethyl((3S,4S,E)-4-methyl-1-(tributylstannyl)oct-1-en-6-yn-3-yloxy)silane
(3'aS,4'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethyltetrahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'(3'H)-one
1-((3aR,6aS)-5',5'-dimethyl-3,3a,4,6a-tetrahydro-1H-spiro[pentalene-2,2'-[1,3]dioxan]-5-yl)-2-tosyldiazene
下游产品
(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one
(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethanol
(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate
(-)-(3aR,4R,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one
5-[(3aS,4R,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(E)-(3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-oct-1-en-6-ynyl]-hexahydro-pentalen-(2E)-ylidene]-pentanal
(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol
(+)-tert-butyl ((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)pentyloxy)dimethylsilane
(+)-(E)-((1S,2R)-2-(2-phenylpropan-2-yl)cyclohexyl)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)acetate
(+)-(tert-butyl)-2-((E)-((3aS,4R,5R,6aS)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethoxy)acetate