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(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol

(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol

CAS号:873949-52-1
英文名:(+)-((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene))pentan-1-ol
分子式:C34H62O3Si2
分子量:575.025
合成路线
上游原料
(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one (+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethanol (-)-tert-butyl ((3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalene]-5'-yloxy)dimethylsilane (+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate (+)-(3'aS,4'R,5'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethylhexahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'-ol (3'aS,4'R,6'aR)-4'-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)-5,5-dimethyltetrahydro-1'H-spiro[[1,3]-dioxane-2,2'-pentalen]-5'(3'H)-one (-)-(3aR,4R,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one (+)-tert-butyl ((E)-5-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)pentyloxy)dimethylsilane (+)-(E)-((1S,2R)-2-(2-phenylpropan-2-yl)cyclohexyl)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)acetate