百科

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

CAS号：874660-86-3

英文名：(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

分子式：C22H36O3

分子量：348.519

合成路线

trimethyl{[(4'aR,4'bR,8'aR,10'aR)-1',1',4'a,7',8'a-pentamethyl-3',4',4'a,4'b,5',6',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-yl]oxy}silane

trimethyl{[(4'aR,4'bR,8'aR,10'aR)-1',1',4'a,7',8'a-pentamethyl-3',4',4'a,4'b,5',6',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-yl]oxy}silane

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(-)-(4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-3,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthren-1(2H)-one

(-)-(4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-3,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthren-1(2H)-one

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(-)-(1R,4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

(-)-(1R,4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(+)-(4'aS,8'R,8'aR,10'aR)-(4'aβ,8'β,8'aβ,10'aα)-3',4',4'a,6',7',8',8'a,9',10',10'a-decahydro-8'-hydroxy-1',1',4'a,8'a-tetramethylspiro[1,3-dioxolane-2,2'(1'H)-phenanthrene]

(+)-(4'aS,8'R,8'aR,10'aR)-(4'aβ,8'β,8'aβ,10'aα)-3',4',4'a,6',7',8',8'a,9',10',10'a-decahydro-8'-hydroxy-1',1',4'a,8'a-tetramethylspiro[1,3-dioxolane-2,2'(1'H)-phenanthrene]

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

上游原料

(-)-(4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-3,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthren-1(2H)-one (+)-(4'aS,8'R,8'aR,10'aR)-(4'aβ,8'β,8'aβ,10'aα)-3',4',4'a,6',7',8',8'a,9',10',10'a-decahydro-8'-hydroxy-1',1',4'a,8'a-tetramethylspiro[1,3-dioxolane-2,2'(1'H)-phenanthrene] trimethyl{[(4'aR,4'bR,8'aR,10'aR)-1',1',4'a,7',8'a-pentamethyl-3',4',4'a,4'b,5',6',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-yl]oxy}silane (-)-(1R,4aR,4bR,8aR,10aR)-7,7-ethylenedioxy-4b,8,8,10a-tetramethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

下游产品

(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol