百科

(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

CAS号：874660-87-4

英文名：(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

分子式：C22H36O4

分子量：364.519

合成路线

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

(-)-(1S,2S,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-1,2,4b,8,8,10a-hexamethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthren-1-ol

上游原料

(4'aR,4'bR,8'R,8'aR,10'aR)-1',1',4'a,7',8',8'a-hexamethyl-3',4',4'a,4'b,5',8',8'a,9',10',10'a-decahydro-1'H-spiro[1,3-dioxolane-2,2'-phenanthrene]-8'-ol

下游产品

(-)-(2R,3S,4aR,4bR,8aR,10aR)-2,3-epoxy-7,7-ethylenedioxy-2,4b,8,8,10a-pentamethyl-1-methylene-1,2,3,4,4a,4b,5,6,7,8,8a,9,10,10a-tetradecahydrophenanthrene