百科

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

CAS号：875631-20-2

英文名：(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

分子式：C23H40O4

分子量：380.561

合成路线

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(3-methoxycarbonyl-1-methyl-2-propenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(3-methoxycarbonyl-1-methyl-2-propenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(2-hydroxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(2-hydroxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8R,9R)-2-(2-acetoxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8R,9R)-2-(2-acetoxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(S)-2-[(2R,3S,6R,8R,9R)-8-((E)-(S)-4-Benzyloxy-3-methyl-but-1-enyl)-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-propionaldehyde

(S)-2-[(2R,3S,6R,8R,9R)-8-((E)-(S)-4-Benzyloxy-3-methyl-but-1-enyl)-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-propionaldehyde

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,3R,6R,8R,8(1R),9S)-2-hydroxymethyl-8-(2-hydroxy-1-methylethyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,3R,6R,8R,8(1R),9S)-2-hydroxymethyl-8-(2-hydroxy-1-methylethyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-hydroxy-3-methylbutyl)-8-(3-methoxycarbonyl-1-methylpropyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-hydroxy-3-methylbutyl)-8-(3-methoxycarbonyl-1-methylpropyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

(2R,2(1R),3S,6R,8S,8(3S),9R)-2-(3-methoxycarbonyl-1-methylpropyl)-8-(3-methyl-4-pentenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

上游原料

(2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-hydroxy-3-methylbutyl)-8-(3-methoxycarbonyl-1-methylpropyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane (2R,2(1R),3S,6R,8R,9R)-2-(2-acetoxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane (2R,3R,6R,8R,8(1R),9S)-2-hydroxymethyl-8-(2-hydroxy-1-methylethyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane (2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(3-methoxycarbonyl-1-methyl-2-propenyl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane (2R,2(3S),3R,6R,8R,8(1R),9S)-2-(4-benzyloxy-3-methyl-1-butenyl)-8-(2-hydroxy-1-methylethyl)-8-formyl-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane (S)-2-[(2R,3S,6R,8R,9R)-8-((E)-(S)-4-Benzyloxy-3-methyl-but-1-enyl)-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-propionaldehyde

下游产品

<2S,2(1R),3S,6R,8S,8(3S),9R>-2-(4-Hydroxy-1-methylbutyl)-3,9-dimethyl-8-(3-methyl-4-pentenyl)-1,7-dioxaspiro<5.5>undecane