百科

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

CAS号：876064-71-0

英文名：(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

分子式：C35H44O5Si

分子量：572.806

合成路线

(3R,4R)-methyl 3,4-epoxyhexanoate

(3R,4R)-methyl 3,4-epoxyhexanoate

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-dihydro-furan-2-one

(4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-dihydro-furan-2-one

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(5R,6S)-5-(tert-Butyl-diphenyl-silanyloxy)-oct-1-ene-3,6-diol

(5R,6S)-5-(tert-Butyl-diphenyl-silanyloxy)-oct-1-ene-3,6-diol

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-tetrahydro-furan-2-ol

(4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-tetrahydro-furan-2-ol

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

(Z,2S,4aS,6S,7R,11aR)-7-tert-butyldiphenylsilanyloxy-6-ethyl-2-(4-methoxyphenyl)-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxabenzocyclononene

上游原料

(4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-tetrahydro-furan-2-ol (3R,4R)-methyl 3,4-epoxyhexanoate (4R,5S)-4-(tert-Butyl-diphenyl-silanyloxy)-5-ethyl-dihydro-furan-2-one (5R,6S)-5-(tert-Butyl-diphenyl-silanyloxy)-oct-1-ene-3,6-diol

下游产品

(Z,2S,3R,8R,9S)-8-tert-butyldiphenylsilanyloxy-9-ethyl-2-methansulfonyloxymethyl-3-(4-methoxybenzyloxy)-2,3,4,7,8,9-hexahydrooxonine (Z,2S,3R,8R,9S)-3-tert-butyldiphenylsilanyloxy-2-ethyl-8-(4-methoxybenzyloxy)-9-((Z)-5-triisopropylsilanylpent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydrooxonine (Z,2S,3R,8R,9S)-8-tert-butyldiphenylsilanyloxy-9-ethyl-2-formylmethyl-3-(4-methoxybenzyloxy)-2,3,4,7,8,9-hexahydrooxonine (Z,2S,3S,8R,9S)-3-bromo-2-ethyl-8-(4-methoxybenzyloxy)-9-((Z)-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydrooxonine (Z,2S,3R,8R,9S)-3-tert-butyldiphenylsilanyloxy-2-ethyl-8-(4-methoxybenzyloxy)-9-((Z)-5-trimethylsilanylpent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydrooxonine (Z,2S,3R,8R,9S)-2-ethyl-3-hydroxy-8-(4-methoxybenzyloxy)-9-((Z)-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydrooxonine