百科

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

CAS号：876133-09-4

英文名：(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

分子式：C25H37IO8Si

分子量：620.546

合成路线

(2R,4aR,6S,7R,8R,8aR)-6-methoxy-8-(3-oxobutylcarbonyloxy)-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine

(2R,4aR,6S,7R,8R,8aR)-6-methoxy-8-(3-oxobutylcarbonyloxy)-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5R,6R)-5-hydroxy-6-hydroxymethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5R,6R)-5-hydroxy-6-hydroxymethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

(2S,3R,4R,5S,6S)-5-tert-butyldimethylsilyloxy-6-iodomethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

上游原料

(2R,4aR,6S,7R,8R,8aR)-6-methoxy-8-(3-oxobutylcarbonyloxy)-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine (2S,3R,4R,5R,6R)-5-hydroxy-6-hydroxymethyl-2-methoxy-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran

下游产品

(2S,3R,4R,5R,6R)-4-hydroxy-2-methoxy-6-methyl-3-phenylcarbonyloxy-5-tert-butyldimethylsilyloxytetrahydro-2H-pyran (2S,3R,4R,5R,6R)-5-tert-butyldimethylsilyloxy-2-methoxy-6-methyl-3-phenylcarbonyloxy-4-trifluoromethylsulfonyloxytetrahydro-2H-pyran (2S,3R,4R,5R,6R)-5-tert-butyldimethylsilyloxy-2-methoxy-6-methyl-4-(3-oxobutylcarbonyloxy)-3-phenylcarbonyloxytetrahydro-2H-pyran