百科

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

CAS号：876405-36-6

英文名：tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

分子式：C51H64O13Si

分子量：913.132

合成路线

ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl trichloroacetimidate

ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl trichloroacetimidate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

2-(trimethylsilyl)ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-di-O-benzyl-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

2-(trimethylsilyl)ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-di-O-benzyl-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

ethyl 2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

ethyl 2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

tert-butyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate

上游原料

ethyl 2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl trichloroacetimidate 2-(trimethylsilyl)ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-di-O-benzyl-6-O-(4-methoxybenzyl)-β-D-glucopyranoside ethyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

下游产品

tert-butyl 2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranosid]uronate