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(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

CAS号：876407-18-0

英文名：(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

分子式：C23H46O5Si

分子量：430.694

合成路线

(3S,4S,5R,6R)-6-(tert-butyldimethylsilyloxy)-2,4-dimethylhept-1-ene-3,5-diol

(3S,4S,5R,6R)-6-(tert-butyldimethylsilyloxy)-2,4-dimethylhept-1-ene-3,5-diol

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(2R,4S,5S)-2-((tert-butyldimethylsilyl)oxy)-5-hydroxy-4,6-dimethylhept-6-en-3-one

(2R,4S,5S)-2-((tert-butyldimethylsilyl)oxy)-5-hydroxy-4,6-dimethylhept-6-en-3-one

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(2S,3R,4S,5R,6R)-6-tert-butyldimethylsilyloxy-2,4-dimethyl-1,3,5-heptanetriol

(2S,3R,4S,5R,6R)-6-tert-butyldimethylsilyloxy-2,4-dimethyl-1,3,5-heptanetriol

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

(S)-2-((4R,5S,6R)-6-((R)-1-(tert-butyldimethylsilyloxy)ethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate

上游原料

(3S,4S,5R,6R)-6-(tert-butyldimethylsilyloxy)-2,4-dimethylhept-1-ene-3,5-diol (2R,4S,5S)-2-((tert-butyldimethylsilyl)oxy)-5-hydroxy-4,6-dimethylhept-6-en-3-one (2S,3R,4S,5R,6R)-6-tert-butyldimethylsilyloxy-2,4-dimethyl-1,3,5-heptanetriol

下游产品

(S)-2-((4R,5S,6R)-6-((R)-1-hydroxyethyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propyl pivalate