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(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

CAS号：87727-91-1

英文名：(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

分子式：C21H36O3Si

分子量：364.594

合成路线

(1R,5R,6S,8R)-6-Bromo-8-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]octan-3-one

(1R,5R,6S,8R)-6-Bromo-8-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]octan-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1S,4R)-7-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]hept-5-en-2-one

(1S,4R)-7-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]hept-5-en-2-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,4R,5S,7S)-5-Bromo-7-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]heptan-2-one

(1R,4R,5S,7S)-5-Bromo-7-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]heptan-2-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

3-(dimethyl-t-butylsilyloxy)-1-iodooct-1-ene

3-(dimethyl-t-butylsilyloxy)-1-iodooct-1-ene

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

(1R,5S,8R)-8-[(E)-(S)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]oct-6-en-3-one

上游原料

(1R,4R,5S,7S)-5-Bromo-7-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]heptan-2-one (1R,5R,6S,8R)-6-Bromo-8-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-2-oxa-bicyclo[3.2.1]octan-3-one 3-(dimethyl-t-butylsilyloxy)-1-iodooct-1-ene (1S,4R)-7-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-oct-1-enyl]-bicyclo[2.2.1]hept-5-en-2-one

下游产品

<5-<3'-(dimethyl-t-butylsilyloxy)oct-1'-enyl>-4-hydroxycyclopent-2-enyl>acetaldehyde (3aS,4R,6aR)-4-{3-[1-(tert-Butyl-dimethyl-silanyloxy)-hexyl]-oxiranyl}-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one 5-(3-t-butyldimethylsilyloxyoct-1-enyl)-4-hydroxycyclopent-2-enylethanol