百科

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

CAS号：879880-55-4

英文名：(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

分子式：C27H54O6Si2

分子量：530.885

合成路线

298691-03-9

methyl 5(S)-(tert-butyldiphenylsilyl)oxy-6-oxo-hexanoate

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-44-1

(3aS,4R,5S,6aR)-methyl [5-(tert-butyldimethylsilyl)oxy-2-oxohexahydro-cyclopenta[b]furan-4-yl]acetate

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-40-7

(3S,3aR,5R,6S,7aS)-3-(tert-Butyl-dimethyl-silanyloxy)-5,6-dihydroxy-octahydro-inden-1-one

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-53-2

7-[(3aS,4R,5S,6aR)-5-(tert-butyl-dimethylsilyl)oxy-2-oxo-hexahydrocyclopenta[b]furan-4-yl]-5-hydroxy-hept-6-enoic acid methyl ester

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-42-9

[3-(tert-butyl-dimethylsilyl)oxy-2-carboxymethyl-5-oxo-cyclopentyl]acetic acid

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-43-0

[3-(tert-butyldimethylsilyl)oxy-2-methoxycabonylmethyl-5-oxocyclopentyl]acetic acid methyl ester

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

879880-47-4

(3aS,4R,5S,6aR)-hexahydro-5-(tert-butyldimethylsilyl)oxy-4-(2-(2-nitrophenylselanyl)-ethyl)-cyclopenta[b]furan-2-one

879880-55-4

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2-(2-hydroxy-ethyl)-cyclopentyl]-hept-6-enoic acid methyl ester

上游原料

methyl 5(S)-(tert-butyldiphenylsilyl)oxy-6-oxo-hexanoate [3-(tert-butyl-dimethylsilyl)oxy-2-carboxymethyl-5-oxo-cyclopentyl]acetic acid (3aS,4R,5S,6aR)-hexahydro-5-(tert-butyldimethylsilyl)oxy-4-(2-(2-nitrophenylselanyl)-ethyl)-cyclopenta[b]furan-2-one (3S,3aR,5R,6S,7aS)-3-(tert-Butyl-dimethyl-silanyloxy)-5,6-dihydroxy-octahydro-inden-1-one [3-(tert-butyldimethylsilyl)oxy-2-methoxycabonylmethyl-5-oxocyclopentyl]acetic acid methyl ester (3aS,4R,5S,6aR)-methyl [5-(tert-butyldimethylsilyl)oxy-2-oxohexahydro-cyclopenta[b]furan-4-yl]acetate 7-[(3aS,4R,5S,6aR)-5-(tert-butyl-dimethylsilyl)oxy-2-oxo-hexahydrocyclopenta[b]furan-4-yl]-5-hydroxy-hept-6-enoic acid methyl ester

下游产品

(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[(1R,2S,3R,5S)-5-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-3-triethylsilanyloxy-cyclopentyl]-hept-6-enoic acid methyl ester