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tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
CAS号:880344-59-2
英文名:tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
分子式:C40H60O6Si2
分子量:693.072
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合成路线
392663-09-1
(S)-3-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-11-5
(S)-1-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-ol
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
880344-55-8
((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methyl pivalate
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-54-6
(S)-3-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-07-9
(2R,3S,5R)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
880344-57-0
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-24-0
2-But-3-enyl-2-{(S)-2-[(2S,3S,5R)-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolane
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-32-0
3-(2-{(S)-2-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-1-{2-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-[1,3]dithian-2-yl}-propan-1-one
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
392663-30-8
3-(2-{(S)-2-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-1-{2-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-[1,3]dithian-2-yl}-propan-1-ol
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
615284-85-0
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
880344-59-2
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
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上游原料
(S)-1-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-ol
(E)-(2S,5S)-6-Benzyloxy-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-methyl-hex-3-en-2-ol
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methanol
((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methyl pivalate
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
(2R,3S,5R)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan
(2R,3S,5R)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-ol
3-(2-{(S)-2-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-1-{2-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-[1,3]dithian-2-yl}-propan-1-one
(2R,3S,5R)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-5-hydroxymethyl-tetrahydro-furan-3-ol
(S)-1-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-one
2-But-3-enyl-2-{(S)-2-[(2S,3S,5R)-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolane
((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methanol
(S)-3-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-propionaldehyde
(2S,3S,5R)-2-((S)-3-Benzyloxy-2-methyl-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan
3-(2-{(S)-2-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-1-{2-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-[1,3]dithian-2-yl}-propan-1-ol
(S)-3-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-propan-1-ol
3-(2-{(S)-2-[(2S,3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-propionaldehyde
下游产品
(E)-5-((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate