百科

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

CAS号：880485-35-8

英文名：(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

分子式：C24H52O3Si2

分子量：444.839

合成路线

(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide

(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

(S)-7,7-diisopropyl-4,8-dimethyl-3-methylene-1,1-bis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,6-dioxa-7-sila-1-boranonane

(S)-7,7-diisopropyl-4,8-dimethyl-3-methylene-1,1-bis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,6-dioxa-7-sila-1-boranonane

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

上游原料

(S)-7,7-diisopropyl-4,8-dimethyl-3-methylene-1,1-bis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,6-dioxa-7-sila-1-boranonane (S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide

下游产品

2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-8-{2-[1-hydroxy-prop-2-(R)-yl]-allyl}-10-methyl-10-(triethylsiloxy)-1,7-dioxaspiro[5.5]undec-2-yl)-acetate 2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-8-{2-[1-triethylsiloxy-prop-2-(R)-yl]-allyl}-10-methyl-10-(triethylsiloxy)-1,7-dioxaspiro[5.5]undec-2-yl)-acetate 2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-10-hydroxy-10-methyl-8-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetate (2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetic acid Acetic acid (2S,4S,6R,8S,10S)-2-(2-benzyloxy-ethyl)-10-hydroxy-10-methyl-8-((R)-3-methyl-2-methylene-4-triisopropylsilanyloxy-butyl)-1,7-dioxa-spiro[5.5]undec-4-yl ester (2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde 2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4,10-dihydroxy-10-methyl-8-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetate (2S,4S,6R,8S,10S)-8-(2-hydroxyethyl)-10-(t-butyldimethylsiloxy)-4-methyl-2-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undecan-4-ol 2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-10-hydroxy-8-{2-[1-hydroxy-prop-2-(R)-yl]-allyl}-10-methyl-1,7-dioxaspiro[5.5]undec-2-yl)-acetate