百科

(E)-5-((2S,3aR,5R,5'R,6R,6''R,7aR)-2-formyl-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

(E)-5-((2S,3aR,5R,5'R,6R,6''R,7aR)-2-formyl-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

CAS号：881651-82-7

英文名：(E)-5-((2S,3aR,5R,5'R,6R,6''R,7aR)-2-formyl-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

分子式：C26H38O7

分子量：462.576

上游原料

(E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-(((methylthio)carbonothioyl)oxy)-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

(E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-(((methylthio)carbonothioyl)oxy)-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

tert-butyl(((2S,3aR,5R,5'R,6R,6''R,7aR)-6-methyl-6''-vinyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane

tert-butyl(((2S,3aR,5R,5'R,6R,6''R,7aR)-6-methyl-6''-vinyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane

(E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-3''-acetoxy-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

(E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-3''-acetoxy-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

上游原料

(E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-(((methylthio)carbonothioyl)oxy)-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate tert-butyl(((2S,3aR,5R,5'R,6R,6''R,7aR)-6-methyl-6''-vinyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane (E)-5-((2S,3aR,3''S,5R,5'R,6R,6''R,7aR)-3''-acetoxy-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate

下游产品

(3S,4S)-6-(2-((R)-hydroxy((2S,3aR,5R,5'R,6R,6''R,7aR)-6''-((E)-5-hydroxypent-1-en-1-yl)-6-methyl-2,3,3a,3',3'',4',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methyl)-1,3-dithian-2-yl)-4-methyl-2-methylenehexane-1,3-diol