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ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

CAS号：882005-07-4

英文名：ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

分子式：C21H32O3

分子量：332.477

合成路线

(2S,4R,6R)-7-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4,6-trimethylheptan-1-ol

(2S,4R,6R)-7-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4,6-trimethylheptan-1-ol

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

(R)-tert-butyldimethyl((2-methylpent-4-en-1-yl)oxy)silane

(R)-tert-butyldimethyl((2-methylpent-4-en-1-yl)oxy)silane

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

(4R,6R)-7-tert-butyldimethylsilyloxy-4,6-dimethyl-1-heptene

(4R,6R)-7-tert-butyldimethylsilyloxy-4,6-dimethyl-1-heptene

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

((2S,4S,6R)-2,4,6-Trimethyl-oct-7-enyloxymethyl)-benzene

((2S,4S,6R)-2,4,6-Trimethyl-oct-7-enyloxymethyl)-benzene

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

ethyl (2E,4R,6S,8S)-9-benzyloxy-4,6,8-trimethyl-2-nonenoate

上游原料

(R)-tert-butyldimethyl((2-methylpent-4-en-1-yl)oxy)silane (4R,6R)-7-tert-butyldimethylsilyloxy-4,6-dimethyl-1-heptene ((2S,4S,6R)-2,4,6-Trimethyl-oct-7-enyloxymethyl)-benzene (2S,4R,6R)-7-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4,6-trimethylheptan-1-ol

下游产品

(2S,4S,6R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-2,4,6,10-tetramethyl-undecanoic acid (3S,5S,6R,8R,10S)-11-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,6,8,10-tetramethyl-undec-1-en-3-ol (2S,4S,6R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-2,4,6,10-tetramethyl-undecanoic acid tert-butyl ester {(2S,3S)-3-[(2S,3R,5R,7S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-octyl]-2-methyl-oxiranyl}-methanol (2S,4R,6R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4,6,10-tetramethyl-undecane-1,9-diol (2S,4S,6R,7S,9S)-9-[(R)-2-[(2-tert-Butoxycarbonylamino-acetyl)-methyl-amino]-3-(3-iodo-4-triisopropylsilanyloxy-phenyl)-propionyloxy]-7-(tert-butyl-dimethyl-silanyloxy)-2,4,6,10-tetramethyl-undecanoic acid tert-butyl ester (E)-(5S,6R,8R,10S)-11-Benzyloxy-5-hydroxy-2,6,8,10-tetramethyl-undec-2-enoic acid ethyl ester