百科

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S,E)-6-((4S,5R,6S)-6-((2R,3S)-3-methoxybutan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)hex-4-en-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S,E)-6-((4S,5R,6S)-6-((2R,3S)-3-methoxybutan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)hex-4-en-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

CAS号：882491-75-0

英文名：(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S,E)-6-((4S,5R,6S)-6-((2R,3S)-3-methoxybutan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)hex-4-en-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

分子式：C48H86O8Si2

分子量：847.363

上游原料

(2S,3R,4S,5S)-3-Methoxymethoxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-enoic acid methoxy-methyl-amide

(2S,3R,4S,5S)-3-Methoxymethoxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-enoic acid methoxy-methyl-amide

(4S,5R,6R,7S,8S)-8-Methoxy-5,7-dimethyl-non-1-ene-4,6-diol

(4S,5R,6R,7S,8S)-8-Methoxy-5,7-dimethyl-non-1-ene-4,6-diol

(2S,3R,4S,5S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-en-1-one

(2S,3R,4S,5S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-en-1-one

(2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester

(2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester

(4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2R,3S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2-methyl-hex-5-en-1-one

(2R,3S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2-methyl-hex-5-en-1-one

(2S,3R,4S,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-ol

(2S,3R,4S,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-ol

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-(4-methoxybenzyloxy)-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-(4-methoxybenzyloxy)-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(3S,4R,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-one

(3S,4R,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-one

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-((R)-1-hydroxybut-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-((R)-1-hydroxybut-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

上游原料

(2S,3R,4S,5S)-3-Methoxymethoxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-enoic acid methoxy-methyl-amide (4S,5R,6R,7S,8S)-8-Methoxy-5,7-dimethyl-non-1-ene-4,6-diol (2S,3R,4S,5S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-triethylsilanyloxy-oct-7-en-1-one (2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate (6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester (4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester (2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate (2R,3S)-1-((S)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-3-hydroxy-2-methyl-hex-5-en-1-one (2S,3R,4S,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-ol (6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-(4-methoxybenzyloxy)-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester (3S,4R,5S,6S)-4-Methoxymethoxy-3,5-dimethyl-6-triethylsilanyloxy-non-8-en-2-one (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-((R)-1-hydroxybut-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate