百科

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

CAS号：883997-18-0

英文名：ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

分子式：C25H40O5SSi

分子量：480.733

合成路线

ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate

ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

(2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide

(2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate

ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

上游原料

ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate (2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate

下游产品

(1R,2R,3S)-2-(hydroxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane (1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane