百科

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

CAS号：883997-21-5

英文名：(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

分子式：C16H34O2Si

分子量：286.525

合成路线

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide

(2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate

ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1S,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-1-(ethoxycarbonyl)ethyl]-3-methylcyclopentane

(1S,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-1-(ethoxycarbonyl)ethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate

ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-7-hydroxy-2,6-dimethyl-2-octenoate

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-7-hydroxy-2,6-dimethyl-2-octenoate

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

(1R,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane

上游原料

ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-7-hydroxy-2,6-dimethyl-2-octenoate ethyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate (2S,3S)-(+)-erythro-3-methylbutane-1,2,4-triol 1,2-acetonide ethyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate ethyl (2E,6S,7S)-7,8-isopropylidenedioxy-2,6-dimethyl-2-octenoate ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate (1S,2R,3S)-2-(tert-butyldimethylsiloxymethyl)-1-[(1S)-1-(ethoxycarbonyl)ethyl]-3-methylcyclopentane

下游产品

(1R,2R,3S)-2-(hydroxymethyl)-1-[(1S)-2-hydroxy-1-methylethyl]-3-methylcyclopentane