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(1R,2S,4aR,5R,6S,8aS)-2-Ethynyl-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
CAS号:885218-82-6
英文名:(1R,2S,4aR,5R,6S,8aS)-2-Ethynyl-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
分子式:C23H38O4Si
分子量:406.631
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合成路线
885218-77-9
(2E,8E,10E)-(S)-13-(tert-Butyl-dimethyl-silanyloxy)-2,6,10-trimethyl-7-oxo-trideca-2,8,10-trienoic acid ethyl ester
885218-82-6
(1R,2S,4aR,5R,6S,8aS)-2-Ethynyl-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
885218-81-5
(1R,2S,4aR,5R,6S,8aS)-2-(2-Hydroxy-ethyl)-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
885218-82-6
(1R,2S,4aR,5R,6S,8aS)-2-Ethynyl-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
上游原料
(2E,8E,10E)-(S)-13-(tert-Butyl-dimethyl-silanyloxy)-2,6,10-trimethyl-7-oxo-trideca-2,8,10-trienoic acid ethyl ester
(1R,2S,4aR,5R,6S,8aS)-2-(2-Hydroxy-ethyl)-5-methoxymethoxy-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
下游产品
(7E,9E,13Z)-(3S,4R,4aR,6aS,11S,12R,18R,20aR,20bS)-4-Hydroxy-12-methoxymethoxy-3,6,11,18,20a-pentamethyl-20-oxo-1,2,3,4,4a,11,12,15,16,17,18,20,20a,20b-tetradecahydro-6aH-19-oxa-cyclohexadeca[a]naphthalene-13-carboxylic acid
(+)-tubelactomicin A
(1R,2S,4aR,5R,6S,8aS)-5-Hydroxy-2-((E)-2-iodo-vinyl)-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester
(7E,9E,13E)-(3S,4R,4aR,6aS,11S,12R,18R,20aR,20bS)-4-Hydroxy-13-(4-methoxy-benzyloxymethyl)-12-methoxymethoxy-3,6,11,18,20a-pentamethyl-1,2,3,4,4a,6a,11,12,15,16,17,18,20a,20b-tetradecahydro-19-oxa-cyclohexadeca[a]naphthalen-20-one
(1R,2S,4aR,5R,6S,8aS)-5-Hydroxy-2-[(1E,3E,7E)-(5S,6R,12R)-12-hydroxy-7-(4-methoxy-benzyloxymethyl)-6-methoxymethoxy-5-methyl-trideca-1,3,7-trienyl]-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid
5-hydroxy-2-[12-hydroxy-7-(4-methoxy-benzyloxymethyl)-6-methoxymethoxy-5-methyl-trideca-1,3,7-trienyl]-1,3,6-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 2-trimethylsilanyl-ethyl ester