百科

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

CAS号：885314-18-1

英文名：S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

分子式：C31H32O5S

分子量：516.648

合成路线

tert-butyldiphenyl(((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-yl)methoxy)silane

tert-butyldiphenyl(((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-yl)methoxy)silane

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methanol

((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methanol

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-ol

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-ol

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methyl) ethanethioate

上游原料

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-ol tert-butyldiphenyl(((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-((trimethylsilyl)ethynyl)tetrahydro-2H-pyran-2-yl)methoxy)silane ((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-ethynyltetrahydro-2H-pyran-2-yl)methanol

下游产品

methyl 2-((2R,3R,4R,5S,6S)-6-((acetylthio)methyl)-3,4,5-tris(benzyloxy)tetrahydro-2H-pyran-2-yl)-2-oxoacetate S-(((2S,3S,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-(bromoethynyl)tetrahydro-2H-pyran-2-yl)methyl) ethanethioate