百科

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

CAS号：886220-90-2

英文名：(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

分子式：C37H72O4Si3

分子量：665.222

合成路线

2,2-Dimethyl-4-triethylsilanyloxy-butyraldehyde

2,2-Dimethyl-4-triethylsilanyloxy-butyraldehyde

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

3,3,7-Trimethyl-1-triethylsilanyloxy-oct-7-en-4-ol

3,3,7-Trimethyl-1-triethylsilanyloxy-oct-7-en-4-ol

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

(E)-1-[(1R,2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyloxy-2-vinyl-cyclopentyl]-2,5,5,9-tetramethyl-6-triethylsilanyloxy-deca-2,9-dien-1-one

上游原料

3,3,7-Trimethyl-1-triethylsilanyloxy-oct-7-en-4-ol 2,2-Dimethyl-4-triethylsilanyloxy-butyraldehyde

下游产品

4-Bromo-benzoic acid (1S,2S,3R,5S)-3-hydroxy-5-methyl-3-((E)-2,5,5,9-tetramethyl-6-oxo-deca-2,9-dienoyl)-2-vinyl-cyclopentyl ester (E)-1-((1R,2S,3R,4S)-1,3-Dihydroxy-4-methyl-2-vinyl-cyclopentyl)-2,5,5,9-tetramethyl-deca-2,9-diene-1,6-dione (E)-1-((1R,2S,3S,4S)-1,3-Dihydroxy-4-methyl-2-vinyl-cyclopentyl)-2,5,5,9-tetramethyl-deca-2,9-diene-1,6-dione