百科

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

CAS号：887602-39-3

英文名：(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

分子式：C39H72O6Si2

分子量：693.156

合成路线

1-[(2R,3S,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enyloxymethyl]-4-methoxy-benzene

1-[(2R,3S,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enyloxymethyl]-4-methoxy-benzene

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

3,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enoic acid 5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-(1-methyl-allyl)-pentyl ester

3,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enoic acid 5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-(1-methyl-allyl)-pentyl ester

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

(2E,8Z)-(4R,5S,7S,10S,11R,12S,14R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-(4-methoxy-benzyloxy)-4,10,12,14-tetramethyl-pentadeca-2,8-diene-1,11-diol

上游原料

3,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enoic acid 5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-(1-methyl-allyl)-pentyl ester 1-[(2R,3S,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-6-enyloxymethyl]-4-methoxy-benzene

下游产品

(7Z,13E)-(2R,4S,5R,6S,9S,11S,12R)-5,9,11,15-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-2,4,6,12-tetramethyl-pentadeca-7,13-dien-1-ol [bis-(2,2,2-trifluoro-ethoxy)-phosphoryl]-acetic acid 3,9,13,15,19-pentakis-(tert-butyl-dimethyl-silanyloxy)-2,6,8,10,16-pentamethyl-1-(1-methyl-penta-2,4-dienyl)-nonadeca-11,17-dienyl ester (3Z,16Z,22E)-(5S,6S,7R,11S,13S,14R,15S,18S,20S,21R)-14,18,20,24-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-5,7,11,13,15,21-hexamethyl-tetracosa-1,3,16,22-tetraen-8-one