百科

(2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-7-(4-methoxy-benzyloxy)-6-(4-methoxy-benzyloxymethyl)-4a-methyl-octahydro-pyrano[3,2-b]pyran

CAS号：889109-05-1

英文名：(2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-7-(4-methoxy-benzyloxy)-6-(4-methoxy-benzyloxymethyl)-4a-methyl-octahydro-pyrano[3,2-b]pyran

分子式：C42H70O8Si2

分子量：759.171

合成路线

858346-53-9

(2R,4aR,6R,7S,8aR,9aS,10aS)-6-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-10a-methyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene

889109-05-1

(2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-7-(4-methoxy-benzyloxy)-6-(4-methoxy-benzyloxymethyl)-4a-methyl-octahydro-pyrano[3,2-b]pyran

上游原料

(2R,4aR,6R,7S,8aR,9aS,10aS)-6-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-10a-methyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene

下游产品

9-[7-benzyloxy-6-(2-benzyloxy-ethyl)-2,6,8a-trimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-4,5a,10-trimethyl-8-vinyl-4a,5a,6,6a,8,9,10,11,11a,12a,13,13a-dodecahydro-2H-1,5,7,12-tetraoxa-cyclohepta[b]anthracene (2S,3R,4aS,6R,7S,8aR)-7-Allyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-6-isopropenyl-4a-methyl-octahydro-pyrano[3,2-b]pyran (2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-6-isopropenyl-7-(4-methoxy-benzyloxy)-4a-methyl-octahydro-pyrano[3,2-b]pyran 2-{3-[7-benzyloxy-6-(2-benzyloxy-ethyl)-2,6,8a-trimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-2-methyl-3-phenylsulfanyl-propyl}-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-ol 1-[(2R,3S,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-3-(4-methoxy-benzyloxy)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-ethanol (2S,3R,4aS,8aS,9aR,10aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracene [(2R,3S,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-3-(4-methoxy-benzyloxy)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol tert-Butyl-[(2S,3R,4aS,8aS,9aR,10aR)-4a,5-dimethyl-2-((R)-2-methyl-3-phenylsulfanyl-propyl)-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-yloxy]-dimethyl-silane (2R,3S,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-2-isopropenyl-8a-methyl-octahydro-pyrano[3,2-b]pyran-3-ol