百科

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

CAS号：890663-86-2

英文名：(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

分子式：C34H52O2

分子量：492.775

合成路线

16-β,26-dihydroxyl cholesterol

16-β,26-dihydroxyl cholesterol

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

Toluene-4-sulfonic acid (2R,6R)-6-((3S,8S,9S,10R,13S,14S,16S,17R)-3-benzyloxy-16-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-heptyl ester

Toluene-4-sulfonic acid (2R,6R)-6-((3S,8S,9S,10R,13S,14S,16S,17R)-3-benzyloxy-16-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-heptyl ester

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

3-O-benzyl diosgenin

3-O-benzyl diosgenin

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

(3S,8S,9S,10R,13S,14S,16S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol

上游原料

Toluene-4-sulfonic acid (2R,6R)-6-((3S,8S,9S,10R,13S,14S,16S,17R)-3-benzyloxy-16-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-heptyl ester 3-O-benzyl diosgenin 16-β,26-dihydroxyl cholesterol

下游产品

(3S,8S,9S,10R,13S,14S,17R)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-1,2,3,4,7,8,9,10,11,12,13,14,15,17-tetradecahydro-cyclopenta[a]phenanthren-16-one (3S,8R,9S,10R,13S,14S,17S)-3-Benzyloxy-17-((R)-1,5-dimethyl-hexyl)-17-hydroxy-10,13-dimethyl-1,2,3,4,7,8,9,10,11,12,13,14,15,17-tetradecahydro-cyclopenta[a]phenanthren-16-one Acetic acid (3S,8R,9S,10R,13S,14S)-3-benzyloxy-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15-dodecahydro-1H-cyclopenta[a]phenanthren-16-yl ester 3-benzyl-16β,17α-dihydroxyl cholesterol