百科

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

CAS号：89460-69-5

英文名：(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

分子式：C17H20O2

分子量：256.339

合成路线

(4aR)-7-methoxy-1,4a-dimethyl-2-oxo-2,4a,9,10-tetrahydrophenanthrene

(4aR)-7-methoxy-1,4a-dimethyl-2-oxo-2,4a,9,10-tetrahydrophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

2,6-dimethyl-1,5-cyclohexadienyl trifluoromethanesulfonate

2,6-dimethyl-1,5-cyclohexadienyl trifluoromethanesulfonate

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

(4aS)-7-methoxy-1,4a-dimethyl-4,4a,9,10-tetrahydrophenanthrene

(4aS)-7-methoxy-1,4a-dimethyl-4,4a,9,10-tetrahydrophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

(S)-(-)-2,3,4,4a,9,10-hexahydro-7-methoxy-1,4a-dimethyl-2-oxophenanthrene

上游原料

(4aS)-7-methoxy-1,4a-dimethyl-4,4a,9,10-tetrahydrophenanthrene (4aR)-7-methoxy-1,4a-dimethyl-2-oxo-2,4a,9,10-tetrahydrophenanthrene 2,6-dimethyl-1,5-cyclohexadienyl trifluoromethanesulfonate

下游产品

(4R,5S,7R,8R,9R,10S,12R,13S,14R,16S)-13,20-Epoxy-16-ethoxy-12-hydroxy-11-oxopicras-2-en-21-oic acid methyl ester [(3aR,5S,6aR,7aS,8R,11aS,11bR,11cR)-3-(tert-Butyl-dimethyl-silanyloxy)-5-ethoxy-8,11a-dimethyl-1,4,5,6a,7,7a,8,11,11a,11b-decahydro-3aH-6-oxa-benzo[de]anthracen-11c-yl]-methanol (4R,5S,7R,8R,9R,10S,12S,14R,16S)-20-(Methanesulfonyl)-16-ethoxy-13-oxo-12-(phenylseleno)-21-norpicras-2-ene (1S,2S,4aS,4bR,9R,10aS)-1,2,3,4,4a,4b,5,6,7,9,10,10a-Dodecahydro-9-hydroxy-2-(methanesulfonyl)-1,4a-dimethylphenanthren-7-one (4R,5S,7R,8R,9R,10S,14R,16S)-20-<(Benzyloxy)methyl>-13-<(tert-butyldimethylsilyl)oxy>-16-ethoxy-21-norpicras-2,12-diene (4R,5S,7R,8R,9R,10S,11S,12S,13S,14R,16S)-13,20-Epoxy-16-ethoxy-11,12-dihydroxypicras-2-en-21-oic acid methyl ester (1R,4aS,4bR,9R,10aS)-9-<(tert-Butyldimethylsilyl)oxy>-1,4,4a,4b,5,6,7,9,10,10a-decahydro-1,4a-dimethylphenanthren-7-one (1R,4aS,4bR,8aS,9R,10aS)-8aβ-<(Benzyloxy)methyl>-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-9α-hydroxy-1α,4aβ-dimethylphenanthren-7-one (1S,2S,4aS,10aS)-1,2,3,4,4a,5,8,9,10,10a-Decahydro-2-(methanesulfonyl)-7-methoxy-1,4a-dimethylphenanthrene (1S,2S,4aS,4bR,10aS)-1,2,3,4,4a,4b,5,6,10,10a-decahydro-2-(methanesulfonyl)-7-methoxy-1,4a-dimethylphenanthrene (1R,4aS,4bR,8aS,9R,10aS)-8a-<(Benzyloxy)methyl>-9-<(tert-butyldimethylsilyl)oxy>-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-1,4a-dimethylphenanthren-7-one (1R,4aS,4bR,8aS,9R,10aS)-8a-<(Benzyloxy)methyl>-9-(2-bromo-1(S)-ethoxyethoxy)-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-1,4a-dimethylphenanthren-7-one (2R,4aR)-2-Ethyl-7-methoxy-1,4a-dimethyl-2,3,4,4a,9,10-hexahydro-phenanthren-2-ol (1R,4aS,4bR,8aS,9R,10aS)-8a-Benzyloxymethyl-7,9-bis-(tert-butyl-dimethyl-silanyloxy)-1,4a-dimethyl-1,4,4a,4b,5,8,8a,9,10,10a-decahydro-phenanthrene (1S,2S,4aS,4bR,9R,10aS)-9-<(tert-Butyldimethylsilyl)oxy>-1,2,3,4,4a,4b,5,6,7,9,10,10a-dodecahydro-2-(methanesulfonyl)-1,4a-dimethylphenanthren-7-one (4R,5S,7R,8R,9R,10S,11R,12S,13S,14R,16S)-13,20-Epoxy-16-ethoxy-11,12-dihydroxypicras-2-en-21-oic acid methyl ester (4R,5S,7R,8R,9R,10S,14R,16S)-20-(Methanesulfonyl)-13-<(tert-butyldimethylsilyl)oxy>-16-ethoxy-21-norpicras-2,12-diene (+)-podocarp-8-en-13-one (4R,5S,7R,8R,9R,10S,13R,14R,16S)-13,20-Epoxy-16-ethoxy-21-nitrilopicrasa-2,11-diene (1R,4aS,4bR,8aS,9R,10aS)-9-<(tert-Butyldimethylsilyl)oxy>-8a-cyano-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-1,4a-dimethylphenanthren-7-one (1S,2S,4aS,10aS)-1,2,3,4,4a,5,8,9,10,10a-decahydro-2-hydroxy-7-methoxy-1,4a-dimethylphenanthrene (4R,5S,7R,8R,9R,10S,12R,13R,14R,16S)-13,20-Epoxy-16-ethoxy-12-(phenylseleno)-21-nitrilopicrasa-2-ene