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(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

CAS号：896435-80-6

英文名：(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

分子式：C16H22O4S

分子量：310.408

合成路线

Phenyl 2,3-O-isopropylidene-6-O-(p-toluenesulfonyl)-1-thio-α-D-mannopyranoside

Phenyl 2,3-O-isopropylidene-6-O-(p-toluenesulfonyl)-1-thio-α-D-mannopyranoside

(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

Toluene-4-sulfonic acid (3aS,4R,6R,7R,7aR)-2,2-dimethyl-4-phenylsulfanyl-7-triisopropylsilanyloxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ylmethyl ester

Toluene-4-sulfonic acid (3aS,4R,6R,7R,7aR)-2,2-dimethyl-4-phenylsulfanyl-7-triisopropylsilanyloxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ylmethyl ester

(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

(3aS,4R,6R,7R,7aS)-7-Methoxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

上游原料

Phenyl 2,3-O-isopropylidene-6-O-(p-toluenesulfonyl)-1-thio-α-D-mannopyranoside Toluene-4-sulfonic acid (3aS,4R,6R,7R,7aR)-2,2-dimethyl-4-phenylsulfanyl-7-triisopropylsilanyloxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ylmethyl ester

下游产品

(2R,3S,4R,5S,6R)-5-Methoxy-6-methyl-2-phenylsulfanyl-tetrahydro-pyran-3,4-diol (2R,3R,4S,5S,6R)-4-Allyloxy-3-methoxy-5-(4-methoxy-benzyloxy)-2-methyl-6-phenylsulfanyl-tetrahydro-pyran (2R,3S,4R,5R,6R)-4-Allyloxy-5-methoxy-6-methyl-2-phenylsulfanyl-tetrahydro-pyran-3-ol