百科

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

CAS号：89708-44-1

英文名：(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

分子式：C18H24F3NO3

分子量：359.383

合成路线

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

(1aR,2aS,4R,6aS,13aS)-4-methyl-10-(2,2,2-trifluoroacetyl)dodecahydro-6H,7H-oxireno[2',3':1,2]indeno[1,7a-e]azonin-6-one

上游原料

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one (((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

下游产品

(2S,4aR,11aS,12S,13aR)-12-Hydroxy-2-methyl-decahydro-indeno[7a,1-h]indolizin-4-one (1S,4R,6S,9R)-4-Methyl-13-aza-tricyclo[7.7.0.01,6]hexadecane-2,8-dione (Z)-(1S,4R,6S)-4-Methyl-13-(2,2,2-trifluoro-acetyl)-13-aza-tricyclo[7.7.0.01,6]hexadec-9-ene-2,8-dione