百科

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

CAS号：898807-19-7

英文名：(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

分子式：C39H76O5Si3

分子量：709.274

合成路线

(5S,6S,8S)-6,8-bi(tert-butyldimethylsiloxy)-1-iodo-5-methoxymethoxy-3-methyl-1,3-nonadiene

(5S,6S,8S)-6,8-bi(tert-butyldimethylsiloxy)-1-iodo-5-methoxymethoxy-3-methyl-1,3-nonadiene

(2E,4E,6E)-1-(tert-butyldimethylsiloxy)-4,6-dimethyl-7-iodo-2,4,6-heptatriene

(2E,4E,6E)-1-(tert-butyldimethylsiloxy)-4,6-dimethyl-7-iodo-2,4,6-heptatriene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(3S,4S,6S)-1,1-dibromo-3-methoxymethoxy-4,6-bi(tert-butyldimethylsiloxy)hept-1-ene

(3S,4S,6S)-1,1-dibromo-3-methoxymethoxy-4,6-bi(tert-butyldimethylsiloxy)hept-1-ene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E)-4,6-dimethyl-7-iodo-2,4,6-heptatrien-1-ol

(2E,4E,6E)-4,6-dimethyl-7-iodo-2,4,6-heptatrien-1-ol

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E)-5-iodo-4-methyl-2,4-pentadien-1-ol

(2E,4E)-5-iodo-4-methyl-2,4-pentadien-1-ol

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

(2E,4E,6E,8E,10E,12S,13S,15S)-1,13,15-tri(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaene

上游原料

(3S,4S,6S)-1,1-dibromo-3-methoxymethoxy-4,6-bi(tert-butyldimethylsiloxy)hept-1-ene (2E,4E,6E)-4,6-dimethyl-7-iodo-2,4,6-heptatrien-1-ol (5S,6S,8S)-6,8-bi(tert-butyldimethylsiloxy)-1-iodo-5-methoxymethoxy-3-methyl-1,3-nonadiene (2E,4E,6E)-1-(tert-butyldimethylsiloxy)-4,6-dimethyl-7-iodo-2,4,6-heptatriene (2E,4E)-5-iodo-4-methyl-2,4-pentadien-1-ol

下游产品

(2E,4E,6E,8E,10E,12S,13S,15S)-13,15-bi(tert-butyldimethylsiloxy)-12-methoxymethoxy-4,6,10-trimethyl-2,4,6,8,10-hexadecapentaen-1-ol