百科

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

CAS号：900519-37-1

英文名：{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

分子式：C35H58O7Si

分子量：618.916

合成路线

2-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-ethanol

2-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-ethanol

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

1-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-6-(4-methoxy-benzyloxy)-hexan-2-one

1-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-6-(4-methoxy-benzyloxy)-hexan-2-one

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

{(2R,6R,8R,10S,13R)-10-[6-(4-Methoxy-benzyloxy)-2-methylene-hexyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-methanol

上游原料

2-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-ethanol 1-[(2S,5R,6R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl]-6-(4-methoxy-benzyloxy)-hexan-2-one

下游产品

5-((2S,5R,6R,8R,10R)-10-[1,3]Dithian-2-ylmethyl-5-methyl-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-ylmethyl)-hex-5-en-1-ol (2S,5R,6R,8R,10R)-10-[1,3]Dithian-2-ylmethyl-5-methyl-2-(2-methylene-6-trimethylsilanyloxy-hexyl)-5-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadecane Triethyl-{(2S,5R,6R,8R,10R)-10-iodomethyl-2-[6-(4-methoxy-benzyloxy)-2-methylene-hexyl]-5-methyl-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-5-yloxy}-silane {(2S,5R,6R,8R,10R)-10-[1,3]Dithian-2-ylmethyl-2-[6-(4-methoxy-benzyloxy)-2-methylene-hexyl]-5-methyl-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-5-yloxy}-triethyl-silane