百科

3-((4aS,6aR,7R,7aS,10S,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one

CAS号：901121-82-2

英文名：3-((4aS,6aR,7R,7aS,10S,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one

分子式：C23H34N2O3

分子量：386.528

合成路线

901121-87-7

(+)-(S)-(1-methyl-5-oxo-hexyl)-carbamic acid tert-butyl ester

901121-82-2

3-((4aS,6aR,7R,7aS,10S,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one

901121-77-5

(+/-)-(2E,4Z)-(4-bromo-1-methyl-undeca-2,4,10-trienyloxy)-tert-butyl-dimethyl-silane

901121-82-2

901121-78-6

(+/-)-3-{(1Z)-1-[(E)-(3-tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-octa-1,7-dienyl}-oxazolidin-2-one

901121-82-2

上游原料

(+/-)-(2E,4Z)-(4-bromo-1-methyl-undeca-2,4,10-trienyloxy)-tert-butyl-dimethyl-silane (+)-(S)-(1-methyl-5-oxo-hexyl)-carbamic acid tert-butyl ester (+/-)-3-{(1Z)-1-[(E)-(3-tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-octa-1,7-dienyl}-oxazolidin-2-one

下游产品

(+)-N-Cbz-2-epi-galbulimima alkaloid 13